Cryogenic Liquid Cylinder Filling- The Venting Dividend

Standard cryogenic liquid cylinder filling procedure for many facilities is to:

1) Connect the source

2) Open the Vent valve; Open the Liquid valve; open the Source

3) Fill by weight

4) Close the Source; Close the Liquid valve; Close the Vent Valve

Others vary Step 4 to:

4+) Close the Source; Close the Liquid valve; Leave the Vent valve open until venting stops (15 minutes to one hour) and then: Close the Vent valve.

The benefits gained from 4+) are significant:

a) High Pressure Liquid Stabilized- When liquid cylinders are filled from a bulk tank with over 40psi there is gas entrapped in the liquid. The higher the pressure of the source tank the more gas is transferred in the liquid. Venting allows this gas to escape instead of crowding up the the liquid cylinders head space building pressure.

b) Hot Liquid Cylinders are Cooled- Liquid Cylinders that sit empty for awhile get warm inside. Allowing the vessel to cool fully prior to closing the vent also reduces the buildup of gas in the head space.

Both of these benefits share the effect of lengthening the flattened, left-hand tail of the pressure building curve. Put another way- Pressure building can be expressed as an accelerating curve. The higher pressure gets the faster the pressure builds steepening the curve to the venting point. The more liquid is allowed to stabilize and cool the longer and flatter the curve.

The net result of all this is that initial time to vent is lengthened and product life is extended.